Wear Ability of Metal Surfaces in Lubrication with Polycomponent Compositions based on Chemical-Modification Rape-Oil

H. O. Sirenko, O. V. Кuzyshyn, L. Ya. Midak

Анотація


The article investigates the processes of bronze-steel pair wear rate during friction on steel 45 (HB 4,45 HPa; Ra0=0,3±0,05 Mm) during lubrification by chemically modified rapeseed oil with multifunctional additives. The objective of work was to establish the influence of sulphur chemically combined with glycerides of rapeseed oil, and also triphenylphosphine and benzotriazole as multifunctional additives and diphenyl sulphourea as a catalist of sulphidation on wear-resistant properties of compositions. There were used mathematical methods of experimentation planning for obtaining of dependency models of wear rate intensity on ingredients content of lubrification composition and methodology of analysis of the obtained regularities by two-dimensional cross-cuts. As a result, we have received the adequate mathematical models of the second order from four factors with response function – volumetric intensity of wear. By the method of fixing of two factors on certain levels there were received partial mathematical models that enabled two dimensional cross-cuts analysis of dependency of response function on two aspects. According to the analysis results there was established that the minimal values of wear rate of tin plated phosphor bronze are observed at minimal concentration of sulphur, triphenylphosphine and benzotriazole (0,1-0,2%) and high content of diphenyl sulphourea in the composition. Increase of sulphur content in the composition leads to increase of minimal values of specific wear rate 10-20 times, and increase of triphenylphosphine content at fixed sulphur concentration - 100 times, and narrowing of the respective area.

Key words: wear, steel, bronze, oil, additives, concentration, rapeseed oil, sulfur.

Посилання:

  1. I.E. Vinogradova, Protivoiznosnye prisadki k maslam (Himija, Moskva, 1972).
  2. I.G. Fuks, Dobavki k plastichnym smazkam (Himija, Moskva, 1982).
  3. A.T. Krachun, V.E. Morar', S.V. Krachun, Trenie i iznos, 11 (5), 929 (1990).
  4. A.Ju. Evdokimov, I.G. Fuks, L.N. Bagdasarov, Smazochnye materialy na osnove rastitel'nyh i zhivotnyh zhirov (CNIITJeIMS, Moskva, 1992).
  5. G. Sіrenko, O. Sav’jak, Vіsnik Prikarpat. un-tu іm. Vasilja Stefanika. Ser. “Hіmіja”, ІІІ, 117 (2002).
  6. O.L. Sav’jak, ІV Vseukraїns'ka naukova konferencіja studentіv ta aspіrantіv «Suchasnі problemi hіmіi» (Kiiv, 2003), s. 106.
  7. O.L. Sav’jak, V regіonal'na konferencіja molodih vchenih ta studentіv z aktual'nih pitan' hіmіi, 2003, s. 41.
  8. O. Sav’jak, Vіsnik Prikarpats'kogo unіversitetu. Serіja «Hіmіja», Vip. ІV, 63 (2004).
  9. G.O. Sіrenko, O.L. Sav’jak, Polіmernij zhurnal, 28 (1), 69 (2006).
  10. V.V. Sinicyn, Podbor i primenenie plastichnyh smazok (Himija, Moskva, 1969).
  11. I.G. Fuks, A.Ju. Evdokimov, A.A. Dzhamalov, Himija i tehnologija topliv i masel, 6, 36 (1992).
  12. L.M. Kirichenko, G.O. Sіrenko, V.І. Kirichenko, Nauk. zb:«Vseukr.nauk. ta prof. tov-va іm. M.Mіhnovs'kogo», 8, 25 (1998).
  13. T.V. Dmitrієva, L.O. Sirovatka, V.І. Bortnic'kij, Kompozicіjnі polіmernі materіali, 25 (1), 66 (2003).
  14. V.І. Kirichenko, G.O. Sіrenko, L.M. Kirichenko, Nauk.-prakt. konf. ”Naukomіstkі tehnologіi podvіjnogo priznachennja”, 1994, s. 76.
  15. T.V. Dmitrieva, L.A. Syrovatka, R.L. Gajduk, Polіmernij zhurnal, 26 (2), 139 (2004).
  16. L.M. Kirichenko, V.І. Kirichenko, V.P. Svіders'kij, G.O. Sіrenko, V. Kovtun, Zb. “Vimіrjuval'na ta obchisljuval'na tehnіka v tehnologіchnih procesah”, 1 (9), 100 (2002).
  17. G.O. Sіrenko, O.L. Sav’jak, V Mіzhnarodna naukovo-tehnіchna konferencіja «Znosostіjkіst' і nadіjnіst' vuzlіv tertja mashin (ZNM-2003)», 2003, s. 64.
  18. G.O. Sіrenko, O.L. Sav’jak, Desjata ukraїns'ka konferencіja z visokomolekuljarnih spoluk, 2004, s.162.
  19. O.L. Sav’jak, V Ukraїns'ka konferencіja molodih vchenih z visokomolekuljarnih spoluk, 2003, s. 39.
  20. B.N. Tjutjunnikov, Himija zhirov (Pishheprom, Moskva, 1974).
  21. L.M. Kirichenko, G.O. Sіrenko, Nauk. zb. «Vseukr.nauk. ta prof. tov-va іm. M.Mіhnovs'kogo», 8, 40 (1998).
  22. L.M. Kirichenko, G.O. Sіrenko, V.І. Kirichenko, V.P. Svіders'kij, 39-ij Mіzhnarod. semіnar po modeljuvannju ta optimіzacії kompozitіv “Racіonal'nij eksperiment u materіaloznavstvі”, 2000, s. 54.
  23. V.І. Kirichenko, L.M. Kirichenko, G.O. Sіrenko, V.P. Svіders'kij, Mіzhnarod. nauk.-tehn. konferenc. “Znosostіjkіst' і nadіjnіst' vuzlіv tertja mashin”, 2001, s. 49.
  24. L.M. Kirichenko, V.І. Kirichenko, V.P. Svіders'kij, G.O. Sіrenko, V. Kovtun, Pracі Mіzhnarodnogo simpozіumu “Tribofatika”, 2, 733 (2002).
  25. G.O. Sіrenko, L.M. Kirichenko, Ukr. konf. “Aktual'nі pitannja organіchnoї ta elementorganіchnoї hіmії ta aspekti vikladannja organіchnoї hіmії u vishhіj shkolі”, 2002, s. 15.
  26. L.M. Kirichenko, V.І. Kirichenko, G.O. Sіrenko, V.P. Svіders'kij, Temat. zb. nauk. prac' tehn. un-tu Podіllja «Problemi suchasnogo mashinobuduvannja», 143 (1996).
  27. L.M. Kirichenko, V.І. Kirichenko, V.P. Svіders'kij, Vіsnik TUP, 3 (1), 95 (2001).
  28. L.M. Kirichenko, V.І. Kirichenko, V.P. Svіders'kij, V.V. Kovtun, Problemi tribologії, 1, 34 (2002).
  29. O.L. Sav’jak, Vseukraїns'ka naukova konferencіja studentіv ta aspіrantіv «Suchasnі problemi hіmії» (Kiiv, 2005), s. 198.
  30. B.L. Litvin, G.O. Sіrenko, O.L. Sav’jak, R.M. Vishnevs'kij, Voprosy himii i himicheskoj tehnologii, 4, 144 (2005).
  31. G.O. Sіrenko, O.L. Sav’jak, O.V. Shijchuk, Problemi tribologії, 2, 139 (2005).
  32. G.A. Sirenko, O.L. Sav'jak, A.V. Shijchuk, Trenie i iznos, 27 (6), 659 (2006).
  33. G.O. Sіrenko, V.І. Kirichenko, L.M. Kirichenko, V.P. Svіders'kij, Mastil'na kompozicіja: Pat. 18077A (Ukraїna), MKІ S10M1/28; S10M1/18. - №95031240. – Zajavl. 20.03.95. – Opubl. 17.06.97. – Bjul. “Promislova vlasnіst'”. – №5. – 1997.
  34. L.M. Kirichenko, V.І. Kirichenko, V.P. Svіders'kij, Plastichna pasta podvіjnogo priznachennja dlja procesіv mehanіchnoї obrobki metalіv: Pat. №71073 (Ukraina), MKІ S10M 129/56, S 10M133/08, S10M 135/00. – №2003076712. – Opubl. 15.11.2004. – Bjul.№11.
  35. L.M. Kirichenko, V.І. Kirichenko, V.P. Svіders'kij, Sposіb oderzhannja bazovoї olivi dlja mastil'nih kompozicіj: Pat. №65753 (Ukraina), MKІ S10M 177/00, S 10M111/06, S07S67/00, S07S319/24. – №2003043787. – Opubl. 15.08.2005. – Bjul.№8.
  36. Koncentrat-pasta podvіjnogo priznachennja dlja procesіv mehanіchnoї obrobki metalіv: Pat. №37362A. – P.r. vіd 5.03.1999 r.
  37. G.A. Sirenko, A.S. Smirnov, Trudy Novocherk. politeh. instituta «Voprosy teorii trenija, iznosa i smazki», 215, 38 (1969).
  38. R.V. Grinevich, V.V. Casjuk, A.S. Smirnov, Primenenie polimernyh materialov (Kartja Moldovenjaskje, Kishinev, 1975).
  39. V.V. Nalimov, N.A. Chernova, Statisticheskie metody planirovanija jekstremal'nyh jeksperimentov (Nauka, Moskva, 1965).
  40. V.B. Tihomirov, Planirovanie i analiz jeksperimenta (Legkaja industrija, Moskva, 1974).
  41. D. Himmel'blau, Analiz processov statisticheskimi metodami (Mir, Moskva, 1973).
  42. L.S. Zazhigaev, A.A. Kish'jan, Ju.I. Romanikov, Metody planirovanija i obrabotki fizicheskogo jeksperimenta (Atomizdat, Moskva, 1978).



Повний текст: PDF
5 :: 0

Посилання

  • Поки немає зовнішніх посилань.